The two American stars of the film Mr. and Mrs. Smith, which opens in North America this weekend, want to be hosts of the Live 8 concerts.
However, unlike their movie scenes where they were sharing scenes, this time the actors will be thousands of miles away from each other.
Brad Pitt would like to host the concert in Philadelphia, while Jolie wants to take part in a European concert.
The Live 8 concerts are taking place in July and will happen simultaneously in six cities, including London, Paris, Philadelphia, Berlin, Edinburgh and Rome. The concerts are being held before the start of the G8 Summit in Scotland.